H_3PO_4/MCM-41催化苯酚与叔丁醇气相烷基化反应(英文)

摘要： The catalytic performance of Al-MCM-41 containing 5-35 wt% H3PO4 was studied for the vapor phase alkylation of phenol with tert-butyl alcohol(TBA) from 383 to 493 K.4-Tert-butyl phenol was produced as the main product with moderate selectivity.The product distribution depends on the reaction temperature,number of acid sites,and the Brnsted to Lewis sites ratios.A lower molar ratio of reactants(TBA/phenol = 2) and a higher space velocity facilitated the production of 4-tert-butyl phenol.The influence of various parameters such as temperature,reactant feed molar ratio,feed rate,and time on stream were investigated for conversion yield and product selectivity. （共6页）